Stainless Steel External Coil Tube for Lithium Precipitation Reactor
Product Overview
The Stainless Steel External Coil Tube (Model: JX-CT-487) is a precision-engineered heat transfer component manufactured by Wenzhou Jixing Metal Materials Co., Ltd. Specifically designed for integration into high-efficiency settling external coil lithium precipitation reactors (沉锂釜), this coil tube serves as the primary thermal exchange medium within lithium-ion battery precursor manufacturing processes. The product is engineered to facilitate efficient heat dissipation and thermal regulation during the lithium carbonate precipitation reaction, ensuring optimal crystallization conditions for battery-grade lithium carbonate production.
This coil tube system represents a critical component in the advanced lithium refining supply chain, providing superior heat transfer performance while maintaining material integrity under harsh alkaline and high-temperature operating environments.
Material & Properties
Base Material
- Primary Alloy: Austenitic Stainless Steel (奥氏体不锈钢), conforming to AISI 316L / ASTM A213 TP316L specifications
- Alternative Grades Available: 304 (AISI 304 / 06Cr19Ni10), 321 (AISI 321 / 06Cr18Ni11Ti), and 904L (AISI 904L / 00Cr20Ni25Mo4Si2) for specialized corrosive environments
- Chromium Content: 16.5–18.5% (minimum 10.5% Cr equivalent for pitting resistance)
- Nickel Content: 10.0–14.5%
- Molybdenum Content: 2.0–2.5% (316L grade) for enhanced chloride resistance
- Carbon Content: ≤0.03% (L-grade) to minimize carbide precipitation during welding
Key Mechanical Properties
- Tensile Strength (UTS): ≥515 MPa (75 ksi)
- Yield Strength (0.2% offset): ≥205 MPa (30 ksi)
- Elongation: ≥40% (minimum, 50 mm gauge length)
- Operating Temperature Range: −196°C to +450°C (−321°F to +842°F)
- Thermal Conductivity: 14–16 W/(m·K) at 25°C
- Corrosion Resistance: Superior resistance to lithium hydroxide solutions, sodium carbonate, and alkaline media at temperatures up to 150°C
Specifications
| Parameter | Specification | Standard / Tolerance |
|---|---|---|
| Outer Diameter (OD) | Φ19.0 mm / Φ25.4 mm / Φ33.7 mm | ±0.15 mm (ASME B36.19M) |
| Wall Thickness | 1.65 mm / 2.11 mm / 2.87 mm | ±10% of nominal |
| Coil Length (per spool) | 15 m – 120 m (configurable) | ±0.5% |
| Bending Radius (minimum) | ≥3.0 × OD | ASME B31.3 |
| Surface Finish | Ra ≤ 0.8 μm (electropolished / passivated) | ASTM A967 / AMS 2700 |
| Pressure Rating (design) | Up to 1.6 MPa (232 psi) @ 200°C | EN 13480-3 |
| Heat Transfer Efficiency | ≥92% (compared to flat-plate baseline) | Internal testing protocol |
| Welding Method | Orbital TIG (GTAW) / Argon arc welding | ASME IX, AWS D10.9 |
| End Connection | Flanged / Threaded / Socket-weld | ASME B16.5 / B1.20.1 |
| Coating (optional) | PTFE-lined / Ceramic-coated inner surface | ASTM B148 |
| Maximum Operating Pressure | 2.5 MPa (363 psi) | Hydrostatic test at 1.5× design pressure |
| Service Life (design) | ≥15 years under standard operating conditions | Accelerated corrosion testing validated |
Manufacturing Process
1. Raw Material Selection & Inspection
Virgin stainless steel seamless tubes are sourced from certified mills meeting ASTM A213 / EN 10216-5 specifications. Incoming material undergoes 100% chemical composition analysis (spectrographic), mechanical property verification, and ultrasonic flaw detection (UT) per ASTM E271.
2. Coil Forming & Cold Bending
The straight tube segments are fed through precision hydraulic coiling machines to form the external coil geometry. Cold bending is performed at ambient temperature to maintain the austenitic microstructure. The bending process is controlled to prevent localized strain hardening, with a minimum bend radius of 3.0 × OD to avoid wall thinning exceeding 10%.
3. Welding & Joining
All longitudinal and circumferential welds are executed using automated orbital TIG (Tungsten Inert Gas) welding with pure argon shielding gas (purity ≥99.995%). Back-purging with argon prevents internal oxidation. Weld parameters are controlled to maintain heat input below 2.5 kJ/mm to prevent sensitization. Post-weld inspection includes:
- Visual inspection (VT) per ASME V, Article 1
- Penetrant testing (PT) per ASTM E709
- Radiographic testing (RT) per ASME V, Article 2 (where required)
- Ultrasonic testing (UT) per ASTM E213 for wall thickness verification
4. Solution Annealing & Pickling
The completed coil assembly undergoes solution annealing at 1050°C ± 25°C followed by rapid water quenching to restore full austenitic structure and eliminate residual stresses. Subsequent pickling removes oxide scale using a nitric-hydrofluoric acid solution, followed by passivation per ASTM A967 to establish a chromium-rich passive film thickness of ≥5 nm.
5. Surface Finishing
For applications requiring ultra-clean surfaces (lithium carbonate crystallization), the internal bore receives electropolishing treatment to achieve a surface roughness of Ra ≤ 0.4 μm, eliminating crevices where lithium salts could accumulate. This process also enhances the passive film uniformity and corrosion resistance by up to 3× compared to mechanical polishing.
6. Final Assembly & Testing
Each coil tube assembly undergoes hydrostatic pressure testing at 1.5 × design pressure (3.75 MPa) with a minimum hold time of 30 minutes. Dimensional verification is performed using laser scanning and coordinate measuring machines (CMM). Final product is packaged in protective moisture-barrier wrapping with desiccant packs for shipment.
Applications
Primary Application: Lithium Carbonate Precipitation Reactors
The JX-CT-487 external coil tube is purpose-engineered for integration into the High-Efficiency Settling External Coil Lithium Precipitation Kettle (高效沉降外盘管式沉锂釜). In this system, the coil tube functions as the external heat exchanger, removing reaction heat generated during the precipitation of lithium carbonate from lithium hydroxide and sodium carbonate solutions. Key application parameters include:
- Process: LiOH + Na₂CO₃ → Li₂CO₃↓ + 2NaOH
- Operating Temperature: 80–120°C (precipitation zone)
- Heat Removal Duty: 45–65 kJ/mol Li₂CO₃
- Product Purity: Battery-grade Li₂CO₃ ≥ 99.5%
Secondary Applications
- Lithium hydroxide concentration and crystallization systems
- Sodium carbonate solution heating in brine processing
- Alkaline leaching reactors in lithium extraction from spodumene
- General-purpose heat exchangers in chemical processing industries requiring corrosion-resistant coil configurations
- Pharmaceutical and food-grade thermal processing systems (316L electropolished grade)
Quality Certifications & Compliance
Manufacturing Certifications
- ISO 9001:2015 — Quality Management System
- ISO 14001:2015 — Environmental Management System
- ISO 45001:2018 — Occupational Health & Safety Management
- NADCAP — National Aerospace and Defense Contractors Accreditation Program (Welding, if applicable)
Product Standards Compliance
- ASTM A213 — Standard Specification for Seamless and Welded Austenitic Stainless Steel Tubing for High-Temperature and High-Pressure Boilers and Heaters
- EN 10216-5 — Technical Delivery Conditions for Seamless Steel Tubes for Pressure Purposes — Austenitic Steels
- ASME BPV Code Section I — Power Boiler and Heating Boiler Construction Rules
- ASME B31.3 — Process Piping
- GB/T 12771 — Chinese National Standard for Stainless Steel Seamless Tubes for Fluid Transport
- JIS G3459 — Japanese Industrial Standard for Stainless Steel Tubes for Chemical Industry
Testing & Verification Reports
- Mill Test Certificate (MTC) per EN 10204 Type 3.1 for each batch
- Positive Material Identification (PMI) via XRF spectroscopy
- Intergranular Corrosion Test per ASTM A262 Practice E
- Pitting Resistance Index (PREN) ≥ 24 (316L grade)
- Hydrostatic Test Report per ASME BPV Code
- Non-Destructive Testing (NDT) Report per applicable code
Unique Selling Points
1. Purpose-Engineered for Lithium Chemistry: Unlike generic stainless steel coils, the JX-CT-487 is specifically designed for the unique corrosive environment of lithium precipitation reactors, with material selection and surface treatment optimized for lithium hydroxide and carbonate media.
2. Superior Heat Transfer Performance: The optimized coil geometry and internal surface finish deliver ≥92% heat transfer efficiency, enabling faster precipitation kinetics and higher throughput in lithium carbonate production.
3. Ultra-Clean Internal Surface: Electropolished interior (Ra ≤ 0.4 μm) prevents lithium salt deposition and product contamination, critical for maintaining battery-grade purity specifications.
4. Extended Service Life: Solution-annealed, passivated, and optionally PTFE-lined configurations provide design life exceeding 15 years, significantly reducing maintenance intervals and total cost of ownership.
5. Full Traceability: Every coil tube assembly is serialized with complete material traceability from mill heat number through final testing, meeting the stringent quality documentation requirements of the battery materials supply chain.